Phosphorus doped carbon nanodots particles based on pomegranate peels for highly active dehydrogenation of sodium borohydride in methanol

Abstract

Here, the carbon nanodots were successfully synthesized from pomegranate peels (PPCD). This obtained PPCD was treated by a hydrothermal process with phosphoric acid for P doping (P doped PPCD) and used as a metal-free catalyst to obtain hydrogen(H2) from so-dium borohydride (NaBH4) methanolysis for the first time. The characteristics of the samples obtained by ultraviolet, fluorescence, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Transmission electron microscopy (TEM) and Inductively coupled plasma mass spectrometry (ICP-MS) analyses were examined. NaBH4 concentra-tion effect, temperature effect and catalyst reusability experiments were carried out. Using 10 mg of the catalyst with 2.5% NaBH4, an HGR value of 13000 mL min-1g-1 was obtained. The activation energy (Ea) for the P-doped PPCD catalyst was 30.96 kJ mol-1.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.