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Influence of process parameters on enhanced hydrogen generation via semi-methanolysis and semi-ethanolysis reactions of sodium borohydride using phosphoric acid

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dc.contributor.authorSaka, Cafer
dc.contributor.authorBalbay, Asım
dc.date.accessioned2019-11-05T12:51:32Z
dc.date.available2019-11-05T12:51:32Z
dc.date.issued2019-10-16
dc.departmentBelirlenecek
dc.description.abstractThe sodium borohydride(NaBH4) semi-methanolysis and semi-ethanolysis reactions to produce hydrogen are investigated using phosphoric acid(H3PO4) for the first time. The NaBH4 concentration, H3PO4 concentration, and temperature parameters on these semialcoholysis reactions are evaluated. The normalized hydrogen generation rates (HGRs) obtained from the NaBH4 semi-methanolysis and semi-ethanolysis acidified using 0.5 M H3PO4 are 11684 and 9981 ml min 1 g 1, respectively. Moreover, the completion times of these semi-methanolysis and semi-ethanolysis reactions with 0.5 M H3PO4 acid concentration are 0.10 and 0.116 min, respectively. Kinetic studies with the power-law model
dc.identifier.issn0360-3199
dc.identifier.scopus2-s2.0-85074085324
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://hdl.handle.net/20.500.12604/869
dc.identifier.wosWOS:000498752900027
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier-Hydrogen Energy
dc.relation.publicationcategoryUluslararası Hakemli Dergi Makalesi
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKG_20241224
dc.titleInfluence of process parameters on enhanced hydrogen generation via semi-methanolysis and semi-ethanolysis reactions of sodium borohydride using phosphoric acid
dc.typeArticle

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